To solve the expression \(2 + 100 \times 4531 - 32\), follow the order of operations (PEMDAS/BODMAS):
First, calculate the multiplication: \[ 100 \times 4531 = 453100 \]
Next, substitute back into the expression: \[ 2 + 453100 - 32 \]
Now perform the addition and subtraction from left to right: \[ 2 + 453100 = 453102 \] \[ 453102 - 32 = 453070 \]
Thus, the final result is: \[ \boxed{453070} \]